well, by looking at the picture, everything seems to be working just fine.
(my guesses are)
You have four virtual drives(the DVD drives letters G, H, I, J) and a single CD drive (E)
And from the pick the system has detected the CD in the CD drive, so it appears to be functioning.

You need to give more information than "it's broken".
Also, if it's IDE then the SATA raid does not effect your CD drive at all. The "Silicon Image SiI 3112 SATA Raid Controller" does not touch your CD drive at all if it's IDE.
That only effects SATA connected devices.

But look up the manual for the system/mobo. You will be able to find everything you need there.